Battery Types, Tips & Technology

Battery technology have evolved greatly in the past few decades.  Batteries may be constructed using one of several available composition technologies.  Below is an explanation of the popular rechargeable and non-rechargeable battery technologies offered by Garden State Battery.  Click a heading below for more information.


Battery Terms

Amperage/Amp Hours (Capacity)
Cell
Charge
Conditioning
Cycle
Discharge
MemoryEffect(voltage depression)

Rechargeable Battery Types:

Sealed Lead Acid (SLA) or "Gel Cell"
Nickel-Cadmium or (NiCd) or "Nicad"
Nickel-Metal Hydride (NiMH)
Lithium Ion

Battery Care and Handling

Overview
Sealed Lead Acid (SLA) or "Gel Cell"
Nickel-Cadmium or (NiCd) or "Nicad"
Nickel-Metal Hydride (NiMH)
Lithium-ion (LiIon)

Battery Charging Technology

Charging Methods
Analyzers & Conditioners

 

 

 

 

Battery Terms

Amperage/Amp Hours (Capacity) (Ah) (mAh = Milliamp hours, or 1/1000 amp per hour)
Represents the amount of energy a battery can hold at the rated voltage.  This measurement helps determine how long the battery will power the equipment it is used in.  Generally speaking, the more 'Ah's,' the longer the run time.  A device which consumes 100mAh per hour will run about 10 hours on a 1000mAh (or 1Ah) battery.

Cell
A single battery cannister.  Usually grouped together with other cells to form battery packs of different voltages.  Example: six 1.2 volt cells group together in series in a battery pack results in a 7.2 volt battery.

Charge
The process of putting energy into a battery.  Required when battery voltage falls below an allowable threshold.

Conditioning
The process of repeatedly charging and deep discharging a battery for the purpose of preventing voltage depression or "memory effect" or to otherwise restore lost capacity.

Cycle
The process of charging and discharging a battery, either through normal use of by a conditioner.

Discharge
The release of energy by the battery.

Memory Effect (voltage depression)
The term used to describe the capacity loss and subsequent voltage drop in a battery due to constant or repetitious charging and incomplete discharging.  This results in a loss of run time.

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Rechargeable Battery Types

Sealed Lead Acid (SLA) or "Gel Cell"
Sealed lead acid or gel cell batteries came about around the early 1960's. This neat invention surfaced from the problems that arose from regular flooded lead acid batteries or wet cells. Wet cells would leak and could only be used in certain positions (upright-like your old car battery). German researchers were the first to develop the electrolyte gel in which the battery acid was suspended in a gel. Then by sealing the battery with the new gelled-electrolyte, you have the basis for the modern "gel-cell" of today. Since the batteries are sealed, and valve regulated for venting, they are relatively leak-proof and can be used in just about any position with out leaking. Today’s gel-cells are very reliable and used for hundreds applications from toys to millitary equipment. You may be familiar with them in your emergency lights, liteboxes, UPS's etc. The only downside to gel cells is that their weight and size makes them impractical for most communications devices where size and weight are important.

Nickel-Cadmium or (NiCd) or "Nicad"
Believe it or not, the nickel-cadmium battery formula is over 100 years old!  They have seen more than 50 years of successful use.  They may be recharged many times, are very tolerant of all types of abuse and are able to deliver power over a very wide temperature range.  Furthermore, they are extremely economical.  Nicad cells are often combined to make the battery "packs" that are power portable 2-way radios, or "Walkie Talkies," cordless tools, radio-controlled cars, razors and countless other devices.

Nickel-Metal Hydride (NiMH)
We've had our customers ask for "Nickel hydroxide" batteries many times; whatever you call them, nickel-metal hydride represents an evolution of nickel-based battery technology.  They pack considerably more punch per pound than their NiCd cousins; NiMH batteries will run your two-way radio up to 40% longer than NiCd's, without adding to the weight.  Furthermore, they do not contain cadmium and are therefore more environmentally friendly.  Quite often, we are able to provide NiMH-based battery packs for the same price as nicads.  Perhaps the most significant feature of NiMH's is that they are resistant to the "memory effect" that often presents a problem with NiCd's

Lithium-ion
Lithium-ion cells are considered to be the latest technology used in mass-produced rechargeable battery packs.  First made commercially available in 1991, they offer the highest power-to-weight/size ratio of any of the popular rechargeable battery types available today.  They are also higher in voltage than NiCd and NiMH batteries, which means less cells are required to meet the voltage requirement of the device being powered.  Add to that zero memory and a long service life and you have a battery pack that is able to meet the demands of today's most popular devices, such as digital cameras, laptop computers and portable music players.

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Battery Care and Handling

Overview
As opinions vary widely as to the best care and handling methods for rechargeable batteries, there is no "definitive" convention available.  We have therefore compiled our own set of guidelines for battery care and handling, which are based both on our many years of experience and on the research of notable battery industry professionals.

Sealed Lead Acid (SLA) or "Gel Cell"
Gel Cell batteries do not like to be fast charged.  Fast charging causes them to heat up excessively, which causes the release of hydrogen and oxygen (also know as " venting" or "gassing").  This release causes the electrolyte gel to dry up.  Gel cells generally like a steady charge rate of about one tenth of their rated capacity or “C/10”. As a general rule of thumb, you should not charge a gel cell at more than 25% of its rated capacity.  The optimum charging for a gel cell would be to charge at 25% or C/4 for about 80% of its capacity, then switch to a slower rate, or "float" for the final 20% of capacity, preferably C/10.  Gel Cells do not develop “memory” like their nickel cadmium cousins, so conditioning, analyzing or deep discharging is not necessary and will actually diminish the useful life of the battery.  Keeping a gel cell in a discharged state for extended periods will also diminish its life.  Storing in a cool, dry place will maximize shelf life.

Nickel-Cadmium or (NiCd) or "Nicad"
NiCD battery "packs," such as those used in 2-way radios, are very durable and require minimal maintenance, however, correct charging methods can greatly increase their performance and overall life. We recommend that you first slow charge batteries which have been stored for an extended period prior to placing in service.  This initial charge (usually at a rate of about 10% of the battery's rated capacity or "C/10") is primarily to redistribute and even the distribution of chemical crystals that form on the battery plates that may have settled during extended storage. New NiCD and NiMH batteries will not reach peak performance until 2-3 cycles of regular use have been achieved.

Today’s NiCD batteries can be fast charged.  The trick, however, is to know when to stop the charge, as overcharging causes overheating, which can damage a battery.  There are many chargers available which monitor battery states and safely charge NiCD's (see Battery Charging Technology).  NiCD batteries self discharge in storage or non-use at roughly 1% per day.  So remember to fully charge your battery after extended periods of non-use.  Charged batteries should be stored in a cool dry place when not in use.  NiCd's are prone to develop memory effect (see definition above).  Memory effect can be relieved by conditioning or deep discharging your battery.  If a conditioner is not available, just try to discharge your battery as much as possible through normal use before recharging. It is normal for NiCD batteries to generate heat during charging however they should not heat up to the point where they cannot be handled.  They should be allowed to cool down prior to being put into service.

Nickel-Metal Hydride (NiMH)
Since NiMH batteries are chemically similar to nickel-cadmium batteries, the same charging and handling rules apply with one major exception: NiMH batteries do not normally require conditioning.  If your batteries are exhibiting memory effect characteristics, conditioning may help restore lost capacity.

Lithium-ion
Lithium-ion batteries do offer obvious advantages over their predecessors, but do not last quite as long.  While nickel-based batteries have been known to last many years in service, LiIon batteries may require replacement more often.  One reason laptop batteries have a high rate of failure is that LiIon cells' life is shortened considerably by exposure to high temperatures.  Recommended storage is at about 50-60 degrees Fahrenheit, at a 40% state of charge.  Other than proper storage, they do not require any conditioning whatsoever.  An advantage of LiIon batteries is their low rate of self-discharge - less than half that of nickel-based batteries.  Additionally, lithium-ion battery chemistry is under constant development and advanced formulas, which feature higher output and improved aging characteristics are emerging every day.

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Battery Charging Technology

Charging Methods
There have been significant advances in battery charging technology in recent years.  Lithium-ion batteries, while very sensitive to charging conditions are actually considered to be simpler to charge than NiCd and NiMH batteries.  This is due to the fact that lithium-ion battery assemblies contain a sophisticated electronic circuit, which precisely controls the charging parameters and provides safety measures. 

The most common and reliable method for charging cadmium-based batteries (NiCd and NiMH) is the "Negative Delta V" method. This method senses a fully charged battery by detecting a drop in cell voltage as the battery reaches capacity. This drop is small but noticeable enough to be detected and signal the charger to shut off or to trickle depending on the charger type. Other chargers use "Delta T" or change in temperature sensors to decide when to stop charging. "Delta T" chargers are less reliable and many manufacturers have adopted the "Delta V" or a combination of the two as their preferred method of choice. 


Analyzers & Conditioners
A battery analyzer is used to determine the battery's ability to store a charge.  By using it, you will be able to tell if a battery is delivering the correct voltage and amperage.  An incorrect voltage reading is usually caused by a dead or shorted cell.  In this case, the battery should be discarded, rebuilt or returned, if under warranty.  A conditioner is a sophisticated device that will perform a series of charge and discharge cycles on a battery.  This is usually done to "break through" the memory barrier that may occur on a Nickel-Cadmium battery or to restore a battery that has remained discharged for a long time.

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